Giel, MC, Smedley, CJ, Moses, JE (January 2021) Sulfur Fluoride Exchange (SuFEx). In: Science of Synthesis. UNSPECIFIED, pp. 435-484.
Abstract
Sulfur Fluoride Exchange (SuFEx) click chemistry is a new generation technology for creating stable molecular connections with absolute reliability under metal-free conditions. SuFEx builds upon the fundamental principles of click chemistry by exploiting a unique blend of stability and latent reactivity of high oxidation state sulfur fluoride [e.g., S(VI)] functionalities to forge stable covalent linkages at connective SuFEx hubs. In this review, we focus mainly on the SuFEx hubs, sulfuryl fluoride (SO2F2), thionyl tetrafluoride (SOF4), ethenesulfonyl fluoride (ESF), 1-bromoethene-1-sulfonyl fluoride (BESF) and, 2-substituted alkyne-1-sulfonyl fluorides (SASFs). We describe each connector's unique reactivity and their application to SuFEx click chemistry.
| Item Type: | Book Section |
|---|---|
| Subjects: | chemistry > techniques > click chemistry > Accelerated SuFEx Click Chemistry chemistry > techniques > click chemistry |
| CSHL Authors: | |
| Communities: | CSHL labs > Moses lab |
| SWORD Depositor: | CSHL Elements |
| Depositing User: | CSHL Elements |
| Date: | 1 January 2021 |
| Date Deposited: | 13 Oct 2023 18:13 |
| Last Modified: | 13 Oct 2023 18:13 |
| URI: | https://repository.cshl.edu/id/eprint/41264 |
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