Burnley, James, Carbone, Giorgio, Moses, John E (March 2013) Catalytic Reduction of ortho- and para-Azidonitrobenzenes via tert-Butoxide Ion Mediated Electron Transfer. Synlett: accounts and rapid communications in synthetic organic chemistry, 24 (5). pp. 652-656. ISSN 0936-5214
Abstract
The reduction of a range of substituted azidonitrobenzene derivatives to the corresponding aniline is described. The chemoselective reaction proceeds cleanly and in good yield, generating minimal waste products. The process involves a thiazolium salt derived species which is proposed as a radical anion relay, with tert-butoxide as the stoichiometric reductant. © 2012 Georg Thieme Verlag Stuttgart · New York.
| Item Type: | Paper |
|---|---|
| Subjects: | chemistry > chemical synthesis chemistry > techniques |
| CSHL Authors: | |
| Communities: | CSHL labs > Moses lab |
| SWORD Depositor: | CSHL Elements |
| Depositing User: | CSHL Elements |
| Date: | March 2013 |
| Date Deposited: | 06 Jul 2021 20:38 |
| Last Modified: | 06 Jul 2021 20:38 |
| Related URLs: | |
| URI: | https://repository.cshl.edu/id/eprint/40248 |
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