Catalyst-Free Regioselective Hydrostannation of Arynes

Spiteri, Christian, Burnley, James, Moses, John E (October 2011) Catalyst-Free Regioselective Hydrostannation of Arynes. Synlett: accounts and rapid communications in synthetic organic chemistry, 2011 (17). pp. 2533-2536. ISSN 0936-5214

DOI: 10.1055/s-0030-1260332


We report the first regioselective hydrostannation of an aryne. Excellent yields were achieved under mild room temperature conditions without the use of additives or catalysts. Preliminary investigations into the effects of substituents have been conducted, revealing impressive levels of regiochemical control. The method also offers a unique route to access 1,2-deuterated arylstannanes demonstrating the power and potential of this chemistry. © Georg Thieme Verlag Stuttgart · New York.

Item Type: Paper
Subjects: chemistry > techniques > click chemistry
CSHL Authors:
Communities: CSHL labs > Moses lab
SWORD Depositor: CSHL Elements
Depositing User: CSHL Elements
Date: October 2011
Date Deposited: 09 Jul 2021 15:50
Last Modified: 09 Jul 2021 15:50
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