Sharma, P., Griffiths, N., Moses, J. E. (September 2008) Biomimetic synthesis and structural revision of (+/-)-tridachiahydropyrone. Org Lett, 10 (18). pp. 4025-7. ISSN 1523-7052
DOI: 10.1021/ol8015836
Abstract
A short synthesis of the revised structure of the marine natural product tridachiahydropyrone is described. A novel biomimetic photochemical electrocyclization was employed to construct the bicyclic carbon framework from an open-chain polyene precursor. The spectroscopic data matched that of the isolated natural product, supporting a revised structure of this complex metabolite.
| Item Type: | Paper |
|---|---|
| Additional Information: | Organic letters |
| Uncontrolled Keywords: | Animals Biological Products/chemical synthesis/chemistry *Biomimetics Cyclization Gastropoda/chemistry Photochemistry Pyrones/*chemical synthesis/chemistry Stereoisomerism |
| CSHL Authors: | |
| Communities: | CSHL labs > Moses lab |
| Depositing User: | Matthew Dunn |
| Date: | 18 September 2008 |
| Date Deposited: | 19 Apr 2021 20:04 |
| Last Modified: | 19 Apr 2021 20:04 |
| Related URLs: | |
| URI: | https://repository.cshl.edu/id/eprint/39534 |
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