Synthesis of Sulfonyl Azides via Lewis Base Activation of Sulfonyl Fluorides and Trimethylsilyl Azide

Barrow, A. S., Moses, J. E. (July 2016) Synthesis of Sulfonyl Azides via Lewis Base Activation of Sulfonyl Fluorides and Trimethylsilyl Azide. Synlett, 27 (12). pp. 1840-1843. ISSN 0936-5214

URL: https://www.thieme-connect.de/products/ejournals/a...
DOI: 10.1055/s-0035-1561626

Abstract

A protocol for the efficient conversion of sulfonyl fluorides into sulfonyl azides through Lewis base activation is described. The in situ generated sulfonyl azides are efficient diazo-transfer agents, affording diazo compounds and primary azides in excellent yields.

Item Type: Paper
Additional Information: Barrow, Andrew S. Moses, John E. Moses, John/I-3731-2017 Moses, John/0000-0003-2162-3234; Barrow, Andrew/0000-0003-3661-5173 1437-2096
CSHL Authors:
Depositing User: Matthew Dunn
Date: July 2016
Date Deposited: 17 Nov 2020 19:57
Last Modified: 17 Nov 2020 19:57
URI: https://repository.cshl.edu/id/eprint/39516

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