A catalytic and tert-butoxide ion-mediated amidation of aldehydes with para-nitro azides

Carbone, G., Burnley, J., Moses, J. E. (April 2013) A catalytic and tert-butoxide ion-mediated amidation of aldehydes with para-nitro azides. Chem Commun (Camb), 49 (27). pp. 2759-61. ISSN 1359-7345

URL: https://pubmed.ncbi.nlm.nih.gov/23443044/
DOI: 10.1039/c3cc40452h

Abstract

We report here a new catalytic reaction in which, para-nitro azides are acylated by aldehydes to produce amides and molecular nitrogen in a single step. The transformation is believed to proceed via an electron transfer process mediated by the tert-butoxide ion, and catalysed by a thiazolium salt derived species.

Item Type: Paper
Additional Information: Chemical communications (Cambridge, England)
CSHL Authors:
Communities: CSHL labs > Moses lab
Depositing User: Matthew Dunn
Date: 7 April 2013
Date Deposited: 08 Jan 2021 21:04
Last Modified: 08 Jan 2021 21:04
URI: https://repository.cshl.edu/id/eprint/39550

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